Designing photoswitches for molecular solar thermal energy storage
نویسندگان
چکیده
منابع مشابه
Evaluating Dihydroazulene/Vinylheptafulvene Photoswitches for Solar Energy Storage Applications
Efficient solar energy storage is a key challenge in striving toward a sustainable future. For this reason, molecules capable of solar energy storage and release through valence isomerization, for so-called molecular solar thermal energy storage (MOST), have been investigated. Energy storage by photoconversion of the dihydroazulene/vinylheptafulvene (DHA/VHF) photothermal couple has been evalua...
متن کاملTemplated assembly of photoswitches significantly increases the energy-storage capacity of solar thermal fuels.
Large-scale utilization of solar-energy resources will require considerable advances in energy-storage technologies to meet ever-increasing global energy demands. Other than liquid fuels, existing energy-storage materials do not provide the requisite combination of high energy density, high stability, easy handling, transportability and low cost. New hybrid solar thermal fuels, composed of phot...
متن کاملPhotoswitchable Molecular Rings for Solar-Thermal Energy Storage.
Solar-thermal fuels reversibly store solar energy in the chemical bonds of molecules by photoconversion, and can release this stored energy in the form of heat upon activation. Many conventional photoswichable molecules could be considered as solar thermal fuels, although they suffer from low energy density or short lifetime in the photoinduced high-energy metastable state, rendering their prac...
متن کاملLow Molecular Weight Norbornadiene Derivatives for Molecular Solar‐Thermal Energy Storage
Molecular solar-thermal energy storage systems are based on molecular switches that reversibly convert solar energy into chemical energy. Herein, we report the synthesis, characterization, and computational evaluation of a series of low molecular weight (193-260 g mol(-1) ) norbornadiene-quadricyclane systems. The molecules feature cyano acceptor and ethynyl-substituted aromatic donor groups, l...
متن کاملMethodology for Designing a Hybrid Thermal Energy Storage Heat Sink
A thermal response model for designing a hybrid thermal energy storage (TES) heat sink is developed. The stabilization time and maximum operating (hot side) temperature-to-transition temperature difference are used to characterize the performance of the heat sink. The thermal properties of the PCM employed in the design are investigated. Integration of a design optimization algorithm into a the...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Tetrahedron Letters
سال: 2015
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2015.01.187